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Improving battery safety with silicones

Potting compounds

Thermal barriers

Coatings

Composite materials

Development of electric vehicles is moving at an astonishing pace, as the energy density of the batteries surges with each successive product generation. This underscores the critical need for a thermal barrier between the battery and the passenger compartment. WACKER silicones can deliver crucial improvements to battery safety and longevity.

The goal: safe, long-lasting EV batteries

These key challenges are the guiding forces behind WACKER’s silicones portfolio for battery safety:

Safe operation

Silicones...

  • Support battery function under normal operating conditions
  • Ensure safe thermal management

Thermal runaway of a cell

Silicones...

  • Interrupt pathways
  • Stop heat transfer

Thermal propagation

Silicones...

  • Limit damage
  • Prevent fire from breaching adjacent battery components

Thermal barriers for insulating batteries

Properties of ELASTOSIL® CM series

  • Provides a flexible, thermally conductive, dielectric elastomer layer
  • Ceramifies at temperatures above 600 °C and forms a hard dielectric layer with reduced thermal conductivity
  • Room-temperature-curing or heat-curing
  • Spraying, coating, laminating

The result is a highly effective surface that provides mechanical stability.

Even more important, however, is the significantly improved heat resistance. In a thermal runaway, temperatures briefly far exceed 1,000 °C. Many carrier fabrics would melt under these conditions.

The ELASTOSIL® CM series prevents exactly that. The silicone elastomers ceramify at high temperatures to form a hard, thermally and electrically insulating layer. This ceramic layer protects the carrier material, keeps it functional and forms a stable barrier against heat and particles.

Properties of composite materials made with high-performance resins:

  • Low fire load (high SiO2 content)
  • Excellent thermal and fire resistance, up to 7 h at 1500 °C for 2-mm composites
  • Ceramification in the event of fire
  • Negligible smoke development, no toxic emissions
  • Superior thermal insulation
  • Thin and suitable for 3D molding
  • Suitable for lightweight designs
  • Passes established industry tests, e.g. UL 94, UL 2596

ELASTOSIL® CM 145 can be applied to a woven fabric, to mica paper or to metal using a fully automated spraying system. Shown here is a standardized gas torch test.

Test parameters:

  • 1-mm thick aluminum plate
  • 1.44-mm thick layer of ELASTOSIL® CM 145
  • See table for heat effects and particle bombardment
No. Time Front-surface temperature Rear-surface temperature
1 200 s 700 °C 202 °C
2 6 s Particle bombardment  
3 100 s 1,200 °C 298 °C

The ELASTOSIL® CM 145 coating is still intact after being subjected to high temperatures for five minutes. The thickness of the coating grows from 1.44 mm to nearly 6 mm. Its electrical strength rises slightly. Volume and surface resistance remain virtually unchanged.

ELASTOSIL® CM 145 Before torch test After torch test
Thickness [mm] 1.44 5.92
Dielectric strength [kV] 18.1 10.1
Volume resistance [Ohm] 7.65E/+11 6.12E/+13
Surface resistance [Ohm] 5.28E/+13 5.19E/+10

ELASTOSIL® CM 145 is an innovative silicone coating for use in battery housings.

This product can provide significant protection for vehicle occupants in the event of thermal runaway.

Properties of ELASTOSIL® R 531/60 and ELASTOSIL® LR 3011/50:

  • Better flexibility at -40 °C than with thermoplastics (PA); pliable
  • Excellent dielectric insulation
  • Heat-resistant (240 h / 205 °C, 3,000 h / 180 °C)
  • Notched bar impact test: no damage to coating and/or no cracking
  • Flame-retardant: ceramifies in response to thermal runaway, forming a stable ceramic that prevents short circuiting.

Other high-performance silicones for batteries

WACKER offers a wide range of specialty silicones for the following applications:

  • Seals (weather packs, housing seals, etc.)
  • Valves
  • Battery coolant connection
  • High-voltage cables
  • Thermally conductive silicone components
  • Silicones for sealing applications

Download: Product guide on e-mobility

32 pages packed with high-performance silicones. Download our guide now!

WACKER silicones for e-mobility

  • Thermal interface materials (e.g. TIM gap fillers, TIM potting compounds)
  • Battery assembly (e.g. busbar coating, seals, valves, coolant connectors)
  • Automotive power electronics (e.g. sealing and bonding, potting and encapsulation)
  • Battery safety (e.g. potting, coating, composite materials)

How can we help move your project forward?

Dr. Martina Schüssler, Chemist & Battery Safety Expert

We are a leading silicones manufacturer with four excellence centers focused on e-mobility issues. Our global teams support OEMs and first-tier suppliers, from the initial concept to series production.

Drop us a line!

Our silicone highlights for batteries