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SILRES® K

SILRES® K is a solution of a condensation curing methyl silicone resin in toluene. The product can be used as a binder or as an impregnation agent for porous materials. Besides SILRES® K is the ideal product for making tack-free prepregs with excellent storage stability.

 

Compared to other WACKER silicone resins SILRES® K gells relatively fast at elevated temperature. It is therefore particularly suitable for fully automated production lines.

 

Fully cured SILRES® K has a very low carbon content and thus yields a high ash content when pyrolized.

 

Composites made of SILRES® K show long-term stability against weathering, moisture and UV light; they can therefore be exposed continuously to constantly changing climatic conditions, UV radiation and temperatures significantly higher than 300 °C (572 °F). SILRES® K further provides water repellency and excellent electrical insulation properties to the respective composite materials.



特性

Uncured:

  • Silicone resin with methyl groups only
  • Liquid (silicone resin solution in toluene)
  • Fast heat curing when catalyzed

 

Cured:

  • Very low carbon content
  • Very high binding strength
  • Excellent heat stability
  • Marginal smoke emission on pyrolysis

SILRES® K的特殊性能

  • 与颜料和填料的相容性
  • 可实现出色的憎水性
  • 憎水性
  • 溶剂型
  • 电绝缘性
  • 缩合固化
  • 耐热性
  • 耐紫外线性和耐候性

免责声明

所提供之所有信息均基于我们当前所掌握的知识。尽管如此,我们不对其作任何担保、也不承担任何责任,并且保留在任何时候进行技术变更的权利。购买方应在预测试中对所提供之信息以及产品在既定应用中的适应性进行检查。任何时候都必须以合同条款与条件为准。此外,本免责申明还适用于与第三方权利有关之事宜,尤其是在德国境外。

  • Impregnation agent for porous materials
  • Binder for composites made of inorganic mineral fillers
  • Binder for laminates made of fibrous fillers, cloths, woven or non-woven reinforcing materials
  • Typical fields of industrial applications: household appliances, mechanical engineering, automotive, electrical industry.

The curing of SILRES® K is accelerated by a number of catalysts. The curing speed depends on the type of curing agent, the catalyst amount and the curing temperature. Please note: curing acceleration is most efficient with liquid catalysts or when the resin is processed in solvent. Adjacent table lists some typical catalysts and the resulting gelling times at 150°C as a function of the catalyst quantity (catalyst quantities given in % by weight, based on solid silicone resin).

 

IMPORTANT: the pot life of catalyzed resin solutions usually is limited, even at room temperature. We therefore recommend to add the catalyst immediately before use and to process the catalyzed mixture within the next few hours.

 

As curing speed may considerably vary within certain limits, these figures are intended as a guideline only. We recommend running preliminary tests to optimize conditions for the particular application.

1. Glass Fibre Laminates

Please note: manufacturing prepregs and laminates is a complex process that needs a thorough control of various process parameters, such as temperature, catalyst quantity, nature of catalyst, solvent type, machine specific conditions, etc. Therefore, the following indications are inteded as a guide only, and we recommend running preliminary tests to optimize the conditions of the particular process.

 

Since fully cured SILRES® K provides water repellency, excellent electrical insulation properties, outstanding heat resistance and long term stability against weathering, moisture and UV light, this silicone resin is often used as a binder for laminates made of fibrous fillers, cloths, woven or non-woven reinforcing materials. The following process illustrates a typical production sequence for the manufacture of glass cloth laminates.

 

SILRES® K is diluted with toluene, or any other suitable organic solvent, to form a resin solution with a solids content of about 10-20 % by weight. The curing catalyst is added right prior processing. For the purpose of storage-stable prepregs WACKER® Catalyst K83 proved most useful; it is added in a quantity of 2 to 5 wt.%, based on the solids content of the silicone resin solution prepared.

 

The glass cloth is then impregnated by the catalyzed silicone resin solution either by spraying, or by running the fabric through an impregnation bath. The solvent subsequently is evaporated in a drying oven at moderate temperature (90 to 110 °C). Please note: the drying temperature must not be too high in order to avoid premature curing of the B-stage resin and of the prepreg web, respectively. Also a very long drying cycle can impair the storage stability of the prepregs made.

 

Depending on the target shape of the laminate product the prepreg web either is rolled-up in layers on a stainless steel mandrel, or it is cut up into smaller pieces which in turn are sandwiched to a layered stack. By applying heat (e.g. 200 °C) and high pressure (for the layered stack assembly: >10 bar) the B-stage resin converts into the C-stage to form a durable and flexurally very rigid composite with very high heat resistance.

 

Please note: inserting a PTFE coated glass fabric between the pressing plates and the layered prepreg stack can help to prevent the composite from sticking to the plates. Besides it has proven useful to first cool the composite down to 80 °C (or lower) before the laminating press is opened, as this minimizes the delamination risk during the decompression phase.

 

2. Mica Laminates

Please note: manufacturing prepregs and laminates is a complex process that needs a thorough control of various process parameters, such as temperature, catalyst quantity, nature of catalyst, solvent type, machine spedific conditions, etc. Therefore, the following indications are inteded as a guide only, and we recommend running preliminary tests to optimize the conditions for the particular process.

 

The process of making mica laminates is similar to the production of glass fibre laminates. Important: the quality of the final product strongly depends on the type of mica, its particle size distribution and the uniformity of the mica paper used.

 

Similar to the process described for glass fibre laminates, the binder-free mica paper is first impregntated by a catalyzed, diluted solution of SILRES® K (solids content of about 10-20 % by weight, which will result in a silicone resin content of approx. 8 to 15 wt.% in the final composite). After a short residence time the solvent is evaporated in a drying oven at moderate temperature (90 to 110 °C) to yield a physically dry, prepreg web that can be rolled-up in layers for storage.

 

For producing mica laminates, the prepreg web is cut up into smaller pieces, sandwiched to a layered stack of desired thickness and pressed for approximately 1 hour at 200 °C under high pressure (>10 bar).

 

Please note: inserting a PTFE coated glass fabric between the pressing plates and the layered prepreg stack can help to prevent the composite from sticking to the plates. Besides it has proven useful to first cool the composite down to 80 °C (or lower) before the laminating press is opened, as this minimizes the delamination risk during the decompression phase. Pressureless post-curing at 250 °C can further improve the lmainate's properties in terms of hardness and cohesive strength.

 

3. Binder for Resistor/Capacitor Coatings

As SILRES® K can be highly filled with mineral fillers, it often is used as binder in coatings for resistors and capacitors. The respective silicone resin based blends are highly fire-retardant, and they safely protect the electrical parts from moisture or any other environmental impact. Besides the thermal management is improved, which extends the lifecycle of the particular electrical element - even when continuously run at high temperature levels.

 

For the production of resistor and capacitor coatings SILRES® K is diluted with toluene, xylene or any other suitable organic solvent, to form a resin solution with a solids content of about 25 to 35 % by weight. Then the finely ground fillers and pigments, which in total account for up to 75 % of the final coating formulation, are added and thoroughly mixed in a kneader. Finally, a curing catalyst (e.g. WACKER® Catalyst F 100%, WACKER® Catalyst K 83 or GENIOSIL® GF 91) is admixed in a quantity of some 1.5 to 3 wt.%, based on the amount of solid silicone resin used. If necessary, more solvent can be added to adjust the consistency of the coating slurry to the particular needs.

 

For coating the respective electrical part is dipped into the slurry; alternatively, resistors can be coated by rolling them over the surface of the slurry. The solvent subsequently is evaporated at moderate temperature, e.g. in a drying oven. Finally the green body is cured at high temperature (150 °C, 90 min.) to give a hard, durable coating of 0.5 to 1 mm thickness. Note: to increase the coating thickness multiple dip-coating is possible.

储存

Store in a dry and cool place.

 

The 'Best use before end' date of each batch is shown on the product label.

 

Storage beyond the date specified on the label does not necessarily mean that the product is no longer usable. In this case however, the properties required for the intended use must be checked for quality assurance reasons.

销售和支持

Wacker Chemicals (China) Co.,Ltd.
Caohejing Hi-Tech Park
200233 Shanghai
中国大陆
+86  21  6130-2000 (电话)
+86 21 6130-2500  (传真)
Contact Sales

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