VINNAPAS® C 305

VINNAPAS® C 305 is a solid, colorless to pale yellowish copolymer of vinyl acetate and crotonic acid.



Properties

  • VINNAPAS® C 305 is a physically drying, thermoplastic binder which forms films through solvent evaporation. When appropriate solvents are used, the dry films are odorless.

Disclaimer

All the information provided is in accordance with the present state of our knowledge. Nonetheless, we disclaim any warranty or liability whatsoever and reserve the right, at any time, to effect technical alterations. The information provided, as well as the product's fitness for an intended application, should be checked by the buyer in preliminary trials. Contractual terms and conditions always take precedence. This disclaimer of warranty and liability also applies particularly in foreign countries with respect to third parties' rights.

Comprehensive instructions are given in the corresponding Material Safety Data Sheets. They are available on request from WACKER subsidiaries or may be downloaded via WACKER web site http://www.wacker.com.

Typical applications for VINNAPAS® C 305:

  • moisture-sensitive adhesives
  • finishes for the textile and hat industries
  • inks for fabrics, leather. Marks made with such inks can easily be removed with slightly alkaline water.
  • lacquers removable by aqueous alkali, often in combination with hard resins.

Processing - Product data

Melt viscosity, 100% Polymer

Bohlin high temperature viscosimeter

100 °C                      ~ 7000 Pa·s

120 °C                      ~ 2000 Pa·s

140 °C                      ~  300 Pa·s

160 °C                      ~   80 Pa·s


Solvents

VINNAPAS® C 305 is soluble in esters, ketones and methanol. Solutions in 94% ethyl alcohol are turbid, but the films deposited from them are almost clear when dry. The resin is only partly soluble in toluene. Solutions with solids contents of up to 50% can be made with good solvents such as acetone and ethyl acetate.

VINNAPAS® C 305 will dissolve in alkaline water, although this is a time-consuming operation resulting in high viscosity solutions. Solution may be speeded up by also using a water soluble solvent and using the following formulation as a guide:

40 parts VINNAPAS® C 305,

35 parts water,

10 parts conc. Ammonia,

30 parts methanol

Acetone may be used instead of methanol. The solution can be diluted by stirring in more water. An alternative method consists of dissolving the resin only in acetone and then diluting the resultant solution with water containing ammonia.

Care should be taken not to exceed a pH value of 8 since otherwise, the resin will be partly saponified and the solution will gel. Dilute caustic potash and certain organic amines can also be used instead of ammonia. Sodium and calcium hydroxide are unsuitable for this purpose since insoluble salts are formed with sodium and calcium ions.

Plasticizers

VINNAPAS® C 305 may be plasticized with the plasticizers normally used for polyvinyl acetate, e. g. dibutyl phthalate and tricresyl phosphate.



 

If the product is used in applications other than those mentioned, the choice, processing and use of the product is the sole responsibility of the purchaser. All legal and other regulations must be complied with.

For questions concerning food contact status according the chapter 21 CFR (US FDA) and German BfR, please feel free to contact us.

Wacker Chemie AG
Hanns-Seidel-Platz 4
D-81737 München
Germany

Packaging

VINNAPAS® C 305 is supplied in 25 kg Paper Bags. Big Bag is available on request.

Storage

To prevent caking VINNAPAS® C 305 should not be stored at temperatures above 20°C. Storage conditions must be dry; material must be protected from direct sun exposure.

Under these conditions the product has a shelf life of at least 12 months starting from the date of receipt.

Sales and support

Wacker Chemical Corporation
3301 Sutton Road
Adrian, MI 49221-9397
United States
+1  888  922-5374 (Phone)
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Products Technical data
Acid number Bulk density Density Glass transition temperature K-value Molecular weight (Mw) Softening point Supply form Viscosity, dynamic
VINNAPAS® B 100/20 VLE - - - - - - approx. 21 °C[4] approx. 69.8 °F[4] - - approx. 185000 g/mol[2] - - - clear, colorless to pale yellow solution in ethyl acetate[1] clear, colorless to pale yellow solution in ethyl acetate[1] 3700 - 4700 mPa·s 3700 - 4700 mPa·s
VINNAPAS® B 60 FG < 0.5 mg KOH/g[7] < 0.5 mg KOH/g[7] 400 - 800 kg/m³ 400 - 800 kg/m³ approx. 1.18 g/cm³[8] - approx. 42 °C[5] - 38 - 42[10] 38 - 42[10] approx. 70000 g/mol[3] approx. 70000 g/mol[3] approx. 119 °C[11] approx. 246.2 °F[11] fine powder, odorless[1] fine powder, odorless[1] - -
VINNAPAS® C 305 30.0 - 38.0 mg KOH/g[7] 30.0 - 38.0 mg KOH/g[7] - - approx. 1.18 g/cm³[8] - approx. 47 °C[6] - 29 - 33[10] 29 - 33[10] approx. 50000 g/mol[3] approx. 50000 g/mol[3] approx. 120 °C[11] approx. 248 °F[11] solid, colorless to pale yellowish flakes - - -
VINNAPAS® UW 1 FS < 0.5 mg KOH/g[7] < 0.5 mg KOH/g[7] 700 - 850 kg/m³ 700 - 850 kg/m³ approx. 1.18 g/cm³[9] approx. 9.848 lb/gal[9] approx. 43.0 °C[6] - 48.0 - 54.0[10] 48.0 - 54.0[10] approx. 145000 g/mol[3] approx. 145000 g/mol[3] approx. 155 °C[11] approx. 311 °F[11] solid, colorless beads[1] solid, colorless beads[1] - -
VINNAPAS® UW 10 FS < 0.5 mg KOH/g[7] < 0.5 mg KOH/g[7] 700 - 850 kg/m³ 700 - 850 kg/m³ approx. 1.18 g/cm³[8] - approx. 44 °C[6] - - - approx. 410000 g/mol[3] approx. 410000 g/mol[3] approx. 220 °C[11] approx. 428 °F[11] solid, colorless beads[1] solid, colorless beads[1] - -
VINNAPAS® UW 2 FS < 0.5 mg KOH/g[7] < 0.5 mg KOH/g[7] 700 - 850 kg/m³ 700 - 850 kg/m³ approx. 1.18 g/cm³[8] - approx. 43 °C[6] - 54 - 60[10] 54 - 60[10] approx. 180000 g/mol[3] approx. 180000 g/mol[3] approx. 167 °C[11] approx. 332.6 °F[11] solid, colorless beads[1] solid, colorless beads[1] - -
VINNAPAS® UW 25 FS < 0.5 mg KOH/g[7] < 0.5 mg KOH/g[7] 700 - 850 kg/m³ 700 - 850 kg/m³ approx. 1.18 g/cm³[8] - approx. 44 °C[6] - - - approx. 540000 g/mol[3] approx. 540000 g/mol[3] - - solid, colorless beads, odorless and tasteless[1] solid, colorless beads, odorless and tasteless[1] - -
VINNAPAS® UW 4 FS < 0.5 mg KOH/g[7] < 0.5 mg KOH/g[7] 700 - 850 kg/m³ 700 - 850 kg/m³ approx. 1.18 g/cm³[8] - approx. 44 °C[5] - 60 - 66[10] 60 - 66[10] approx. 280000 g/mol[3] approx. 280000 g/mol[3] approx. 197 °C[11] approx. 386.6 °F[11] solid, colorless beads - - -
Legend
[1] Supply form | Visual,  [2] Molecular weight Mw of the polymer | SEC, PS-Standard,  [3] Molecular weight (Mw) | SEC, PS-Standard,  [4] Glas transition temperature of the polymer | DSC (DIN 53765 / ISO 11357-5),  [5] Glass transition temperature | DSC (DIN 53765 / ISO 11357-5),  [6] Glass transition temperature | DSC DIN EN ISO 11357-2,  [7] Acid number | specific method,  [8] Density of the polymer | DIN EN ISO 1183 /1-3,  [9] Density | DIN EN ISO 1183 /1-3,  [10] K-value | DIN 53726,  [11] Softening point | ASTM D 3104 

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